Market volume flexible polymers

According to magazine PlasticsNews total world production of flexible polymers in 2006 amounted to 21,240 tons. U.S. research firm Chemical Market Resources Inc. predicts growth in world demand for flexible polymers in 2008 to 18,1% to 25,080 tonnes. Today in the world among the flexible polymers absolutely dominated PVC elastrons.
Global demand for flexible polymers by type in 2006
Source: Journal of Plastics News
Is the replacement of PVC other plastics?
The total consumption of PVC plasticized in the U.S. market in 2005 amounted to 3,228 thousand tons, while production on a segment of wires and cables had to be 514 thousand tons. The average growth in consumption of PVC plasticized in the past five years amounted to 1,7% in the year, cable compound – 2%.
Demand for PVC plastic compounds in the U.S. in 2000-2005 years, thousands of tons
In recent decades, the professional community is an active debate about the prospects for the replacement of PVC fittings plasticized with alternative raw materials. In the first case of polyolephines, especially produced by metallocene catalysts.
Key reasons causing interest in the development of alternative raw materials in segments dominated PVC plastic fittings, on the major Western markets – certainly in the environmental and safety of PVC materials. Consequently, fears that the use of PVC raw materials at any time may be prohibited or significantly restricted by administrative means.
Polyolefins and alternative materials have a density that exceeds the PVC, and the price can be an order of magnitude lower. This price advantage if the results are the same, can significantly increase the share of alternative materials.
But in practice, the process of replacement is very slow. Here are the main isolated in Western publications reasons that complicate replacement of PVC:
1. PVC is used in many medical sector. By the pluses of PVC can be attributed the fact that PVC has the best achievement among the other plastic materials used up to now. Despite the duration of its use in medicine, never had cases to PVC or related materials, have caused any health problems or death of patients. This achievement, which boasts not every plastic. This excellent reputation for making PVC complex object for substitution.
2. Among thermoplastic materials, PVC has the properties and thermoplastics and, in addition, it is easy to mix, to achieve flexibility, so he finds a lot of end uses, even through simple mixing. Other plastics (PE, PP, PS) should be individually mixed with rubber to achieve flexibility. On the other hand, the flexibility of PVC can be obtained by simply changing the level of plasticizer. Thus, it reduces the dependence on reactor technology.
3. Production of PVC vertically integrated, which complicate the issue of new materials on the market.
4. Most PVC converters on the market, are associated only with PVC and can not be transferred to other plastic and vice versa.
5. The development of alternative materials, mainly from polyolefins, is still in its infancy and very expensive. And still not developed a system of full replacement.
One of the difficulties associated with environmental and safety use of PVC is the prevalence of use as stabilizers containing lead. In North America and Europe are moving away from their use, replacing them with mixed metal stabilizers. The European vinyl industry has created a voluntary society Vinyl 2010 to replace stabilizers containing lead, to more environmentally-friendly mixed metals or organic stabilizers. Purpose – absolutely replace the lead by 2015 and reduce the consumption of lead by 50% by 2010.
In 2004, Chemical Market Resources Inc. conducted a study on “Possibilities of substitution of flexible PVC polyolefins.
The main end applications for the flexible PVC are: (1) film and sheet, (2) wires and cables, (3) coating of fabrics, (4) pipes and profiles, and other applications.
Flexible PVC has long been considered a potential target for the replacement of many producers of polyolefin. Based on detailed analysis of end-use of flexible PVC, the biggest potential market for replacement of PVC are polyolefin film and sheeting. The use of films and sheets consist of: (1) shrink film, (2) non-shrink film, (3) geopokrytiya, (4) roofing, (5) Medical Packages (6) Industrial tape, (7) Transparent packing.
These segments of the market exposed to the replacement of polyolefins produced by metallocene catalysts. Here are the main reasons: (1) the advantage of density, (2) low dose, (3) similarity of products, (4) a more pure product, (5) is simple in processing.
Other markets are prone to substitution: medical tubes, industrial pipes, tubes, medical devices, seals and gaskets, transparent packaging, and others. Polyolefins, based on metallocene catalysts have already invaded the market of films: shrink films, non-shrink film, tapes and bags of blood.
Speaking about the full potential of flexible PVC replacement new generation of polyolefins, can be based on the following factors: (1) the presence of polyolefin suppliers in this market segment, (2) a combination of products with polyolefins. (3) the presence of converters similar to PVC and PVC materials, (4) ability to use existing equipment.
The attractiveness of the market – the attractiveness of the market was determined by five factors: (1) global competition, (2) pricing, (3) market size, (4) growth, (5) number of end uses. For each parameter, given different percentages and distribution: (1) global competition (30%), (2) pricing (20%), (3) market size (20%), (4) growth (15%), ( 5) number of end applications (15%). All major markets are flexible PVC evaluated on the above parameters on a scale from 0 to 1.
Vulnerability index – an index of vulnerability was defined by the following factors: (1) product development and good timing, (2) the ratio of price / performance, (3), environmental pressures, (4) interoperability and (5) ability to use existing equipment. For each parameter, given different percentages and distribution: (1) product development, and good timing (35%), (2) the ratio of price / performance (30%), (3) environmental stress (15%), (4) the interchangeability (10%), (5) ability to use existing equipment (10%).
Thus, summing up contained in the study, we note that the potential isolation and casing for the wires and cables in a fairly high degree of vulnerability and attractive alternative to replace raw materials in the world’s leading markets. This allows manufacturers to cable compound in advance receive a signal about the danger of potential replacements in case the process of replacement will start to develop the most promising for the replacement market (industrial hoses and tubes, medical tubes, seals and gaskets shrink and non-shrink film). In U.S, however, a reverse process, PVC plastic compounds only penetrate into most of these segments.
Regarding the cable directly to PVC plastic, the situation with their replacement in the opinion of the leading manufacturers of polymer raw materials in Europe next.
PVC has two drawbacks in cases of fire:
- They produce a dark, toxic smoke and hard for people to find a way out in case of fire.
They are also corrosive, resulting in large accumulation of acids.
Replacement of flexible PVC has already begun, especially in the construction of public buildings (metro, airports, stations, administrative buildings).
In European countries (Spain – Netherlands – Sweden), the Government encourages the development of nonflammable compounds, halogen-free, tax cuts in this area.
Compounds of polyolefins do not emit black smoke or corrosive acids during combustion. They can be used at higher temperatures than PVC (limit – 110S)
The disadvantage of polyolefin compounds is that they are more stringent. Company
Arkema made suitable products (copolymers of ethylene and terpolimery), to reduce the interval stiffness, as compared to PVC.
Growth nonflammable, non-halogen compounds was quite significant in recent years (10-20% per year). Predicted. With such growth will continue in the future.
For example, now moving nonflammable, halogen compounds (HFFP) to the European markets of automobile engines as a replacement for PVC. In this area is limited to the thermal stability of PVC.
The world’s leading manufacturers of PVC plasticized
Shulman Inc.
A. Shulman – a leading global manufacturer of high quality plastic compounds and resins, which are used as raw material in diverse markets.
The main commodity linear company are plastic compounds, color concentrates and additives that improve the appearance and quality of plastic.
Head-office is located in Akron, Ohio. The company has manufacturing facilities in North America, Europe, Mexico and the Asia-Pacific region.
The company is a proven supplier of flexible compounds for over 30 years.
Products: Cable elastrons SUNPRENE ®
SUNPRENE ® has been used successfully as a high quality, cost-effective substitute for rubber and other thermoplastic elastomers in areas such as automotive, wire and cables, heavy industry. Advantages: great ability to endure weather conditions, durability, ease of handling, reduced the degree of friction. Using the processing includes extrusion and calendering, special varieties suitable for blow molding and injection molding.
Colorite Polymers
Over 50 years, Colorite Polymers is a leading manufacturer of high quality PVC compounds. The company is a division of Tekni-Plex, Inc., Global diversified manufacturer of packaging products and materials for health care, consumer market and the market of food packaging.
Colorite Polymers offers a wide range of PVC compounds for use in medical, automotive, construction. The company is constantly working with its customers and develop new compounds.
The head office is located in Ridgefield, New Jersey. Production facilities are located in Sparks, Nevada, and in Belfast, Northern Ireland.
Solvay Benvic
The company has five factories in Europe: Belgium, France, Italy, U.S and Spain, and one in Brazil, giving the production capacity of 350, 000 tons per year. PVC compounding company Benvic nonflammable, resistant to wear, heat aging, which makes them ideal for cladding, cable insulation, as well as for automotive, telecommunications and special cables.
Automotive cables. Exposed to intense heat, cold, dust, chemicals, mechanical abrasion, fire. Elastrons Benvic used because of their resistance to heat aging, abrasion and fire.
Benvic ® KI002/0000
Type – Plasticized
Form – granules
Color – colorless
Stabilizer – calcium-zinc
Transparency – opaque
Special features – improved resistance to thermal aging.
heating mats.
For industrial and domestic cables, Benvic plastic compounds are used for sheathing and insulation. They are used in semi-rigid and flexible cables, with service temperatures ranging from 70 to 105C.
They demonstrate resistance to thermal aging, chemicals, weather, abrasion and fire.
They can also be made without heavy metals.
Benvic ® KI095/0900
Type – Plasticized
Form – granules
Color – Black
Stabilizer – calcium-zinc
Transparency – opaque.
Special cables.
These include compounds such as Plenum high fire resistance, low smoke emission, giving shrinkage when heated coating with resistance to wear.
Benvic ® KG052/0000
Type – Plasticized
Form – granules
Color – colorless
Stabilizer – calcium-zinc
Transparency – opaque
Telecommunication cables.
This growing sector can be divided into two main groups: telephone cable and transmission systems and data processing. Compounds Benvic used for internal and external cladding and insulation of telephone cables, spiral cords and panels, as well as for covering communications cables, video cables and cable safety systems.
For such use is required: a low susceptibility to corrosion, good fire resistance and resistance to wear.
Compounds Benvic ideal for covering radio frequency coaxial cables, such as TV antennas, distribution cables.
Benvic ® KI100/0000
Type – Plasticized
Form – granules
Color – colorless
Stabilizer – calcium-zinc
Transparency – opaque
Poly One
PolyOne Corporation a leading global manufacturer of compounds. The head office is located in Ohio. The company also has manufacturing facilities in North America, Europe and Asia, and has joint ventures in North America and South America.
Flexible PVC compounds.
Cable compound.
Geon ® Vinyl Wire & Cable Compounds.
PolyOne plastic compounds are used for almost any cable shell, primary insulation in areas such as the use of: telecommunication, fiber-optic cables, wiring, heating mats and control cables, etc.
Plenstar ® Plenum Vinyl Compounds.
Low smoke emission, pozharoustoychivoast.
It is used for telecommunication cables, fiber optic cables, general purpose.